4539-77-9

Basic information

• Product Name: DIMETHYL 2,4:3,5-DI-O-METHYLENE-D-GLUCARATE
• Synonyms: DIMETHYL 2,4:3,5-DI-O-METHYLENE-D-GLUCARATE;2,4:3,5-Di-O-Methylene-D-glucaric Acid DiMethyl Ester
• CAS NO: 4539-77-9
• Molecular Formula: C10H14O8
• Molecular Weight: 262.21336
• Product Categories: 13C & 2H Sugars;Carbohydrates & Derivatives
• Mol File: 4539-77-9.mol
• Article Data: 1

Chemical Properties

• Melting Point: 106-107 °C
• Boiling Point: 321.1±42.0 °C(Predicted)
• Appearance: /
• Density: 1.325±0.06 g/cm3(Predicted)
• Solubility: Chloroform, Methanol
• CAS DataBase Reference: DIMETHYL 2,4:3,5-DI-O-METHYLENE-D-GLUCARATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIMETHYL 2,4:3,5-DI-O-METHYLENE-D-GLUCARATE(4539-77-9)
• EPA Substance Registry System: DIMETHYL 2,4:3,5-DI-O-METHYLENE-D-GLUCARATE(4539-77-9)

Safety Data

• Hazardous Substances Data: 4539-77-9(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

Dimethyl 2,4:3,5-Di-O-methylene-D-glucarate (cas# 4539-77-9 ) is a compound useful in organic synthesis.

Upstream product

• 90-80-2 D-Glucono-1,5-lactone 
• 5323-77-3 2,4:3,5-dimethylene-D-gluconic acid 
• 5334-20-3 2,4:3,5-di-O-methylene-D-glucitol 
• 122174-81-6 1,6-di-O-benzoyl-2,4:3,5-di-O-methylene-D-glucitol 
• 7437-68-5 O²,O⁴;O³,O⁵-dimethanediyl-D-glucaric acid 
• 7437-68-5 O²,O⁴;O³,O⁵-dimethanediyl-D-mannaric acid 
• 50-00-0 formaldehyd 
• 576-42-1 D-glucaric acid monopotassium salt 

Downstream Products

• 80876-59-1 saccharic acid 1,4-lactone 
• 80876-58-0 L-idaric acid 

Relevant articles and documents

SYNTHESIS OF L-IDARO-1,4-LACTONE, AN INHIBITOR OF α-L-IDOSID-URONASE

L-Idaro-1,4-lactone was synthesized by two different, published methods: (1) epimerization of monopotassium D-glucarate by refluxing in aqueous barium hydroxide, and (2) oxidation of L-iditol by heating in dilute nitric acid.The lactone, formed by heat dehydration from aqueous solution at low pH, was purified by paper chromatography, and quantitated by gas-liquid chromatography using inositol as the internal standard.The monolactone inhibited human, seminal-fluid α-L-idosiduronase activity, with either phenyl or 4-methylumbelliferyl α-L-idosiduronic acid as the substrate, to the same degree as D-glucaro-1,4-lactone inhibits α-D-glucosiduranose.