454450-91-0Relevant academic research and scientific papers
Enantioselective synthesis of (-)-idiospermuline
Overman, Larry E.,Peterson, Emily A.
, p. 6905 - 6919 (2007/10/03)
The enantioselective total synthesis of the nonacyclic polypyrrolidinoindoline (-)-idiospermuline is described. Stereocontrolled formation of the vicinal quaternary carbon centers is achieved in a single step by dialkylation of an unsymmetrical prostereog
Enantioselective total synthesis of quadrigemine C and psycholeine
Lebsack, Alec D.,Link,Overman, Larry E.,Stearns, Brian A.
, p. 9008 - 9009 (2007/10/03)
The first total syntheses of higher-order members of the polypyrrolidinoindoline alkaloid family are reported. The synthesis of quadrigemine C (1) and psycholeine (3) begins with synthetic meso-chimonanthine (4), which is synthesized from commercially ava
