454704-43-9Relevant academic research and scientific papers
Totally diastereoselective synthesis of a new chiral quinoline diazaphospholidine ligand and its derivatives
Delapierre, Guillaume,Achard, Mathieu,Buono, Gérard
, p. 4025 - 4028 (2002)
QUIPHOS-PN5, a new stable P,N ligand with a stereogenic phosphorus centre was synthesised in two steps from 8-bromoquinoline (61% yield). Its structure and its bidentate chelating ability was confirmed by the X-ray structure of a palladium(II) complex with this ligand. P(V) derivatives of QUIPHOS-PN5 were then easily obtained in excellent yields (85-100%).
