4556-72-3Relevant academic research and scientific papers
Synthesis and characterization of in-chain silyl-hydride functional SBR and self-crosslinking elastomer
Wang, Bai,Ma, Hong Wei,Shen, Kai Hua,Jun, Ding,Li, Yang
, p. 1419 - 1422 (2012)
Functional in-chain silyl-hydride (Si-H) SBR copolymers of 4-vinyiphenyldimethylsilanol (VPDMS) and butadiene were synthesized by living anionic polymerization, in which active group Si-H was not lost and its content was controllable. Corresponding self-c
Synthesis and characterization of novel liquid crystalline polystyrene
Wang, Bai,Ma, Hong Wei,Wang, Yan Shai,Li, Yang
, p. 915 - 917 (2013)
The paper introduces a simple method to synthesize novel liquid crystalline polystyrene (LC-PS) containing a mesogenic unit at a side chain by hydrosilylation through poly[(4-vinylphenyl)dimethylsilanol] (PVPDMS) and liquid crystal monomer cholesteryl 4-[4-(undec-10-enoyloxy)benzoyloxy]-phenyladipate (M). The LC-PS had high purity, high molecular weight, narrow distribution, good thermal stability, and typical thermotropic liquid crystallinity (SA phase), as shown by 1HNMR analyses, size exclusion chromatography (SEC) thermogravimetry analysis (TGA), differential scanning calorimetry (DSC), polarizing optical microscopy (POM), and X-ray diffraction (XRD). The glass-transition temperature (Tg) of LCPS was much lower than that of PVPDMS, while the clearing point (Ti) of LC-PS significantly increased compared with M.
Selective Manganese-Catalyzed Oxidation of Hydrosilanes to Silanols under Neutral Reaction Conditions
Wang, Kaikai,Zhou, Jimei,Jiang, Yuting,Zhang, Miaomiao,Wang, Chao,Xue, Dong,Tang, Weijun,Sun, Huamin,Xiao, Jianliang,Li, Chaoqun
supporting information, p. 6380 - 6384 (2019/05/06)
The first manganese-catalyzed oxidation of organosilanes to silanols with H2O2 under neutral reaction conditions has been accomplished. A variety of organosilanes with alkyl, aryl, alknyl, and heterocyclic substituents were tolerated, as well as sterically hindered organosilanes. The oxidation appears to proceed by a concerted process involving a manganese hydroperoxide species. Featuring mild reaction conditions, fast oxidation, and no waste byproducts, the protocol allows a low-cost, eco-benign synthesis of both silanols and silanediols.
Heme Protein Catalysts for Carbon-Silicon Bond Formation In Vitro and In Vivo
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Paragraph 0270; 0271, (2017/08/26)
The present invention provides compositions and methods for catalyzing the formation of carbon-silicon bonds using heme proteins. In certain aspects, the present invention provides heme proteins, including variants and fragments thereof, that are capable of carrying out in vitro and in vivo carbene insertion reactions for the formation of carbon-silicon bonds. In other aspects, the present invention provides methods for producing an organosilicon product, the method comprising providing a silicon-containing reagent, a carbene precursor, and a heme protein; and combining the components under conditions sufficient to produce an organosilicon product. Host cells expressing the heme proteins are also provided by the present invention.
