457614-07-2Relevant articles and documents
Enantioselective allyltitanation. Synthesis of (-)-slaframine
Cossy, Janine,Willis, Catherine,Bellosta, Ve?ronique,Saint-Jalmes, Laurent
, p. 951 - 957 (2007/10/03)
An enantioselective synthesis of the indolizidine alkaloid (-)-slaframine from aldehyde 1 is reported. The stereogenic centers at C-1 and C-8a are introduced by an enantioselective allyltitanation and a Mitsunobu reaction. Reductive double cyclization of