457630-02-3

Basic information

• Product Name: Benzenesulfonamide, N-[3-(1,1-dimethylethyl)-3,4-pentadienyl]-4-methyl-
• CAS NO: 457630-02-3
• Molecular Formula: C16H23NO2S
• Molecular Weight: 293.43
• Mol File: 457630-02-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-[3-(1,1-dimethylethyl)-3,4-pentadienyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-[3-(1,1-dimethylethyl)-3,4-pentadienyl]-4-methyl-(457630-02-3)
• EPA Substance Registry System: Benzenesulfonamide, N-[3-(1,1-dimethylethyl)-3,4-pentadienyl]-4-methyl-(457630-02-3)

Safety Data

• Hazardous Substances Data: 457630-02-3(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 390816-76-9 3-tert-butyl-penta-3,4-dienoic acid ethyl ester 
• 55930-38-6 3-(tert-butyl)penta-3,4-dien-1-ol 
• 52323-98-5 4,4-dimethylpent-2-yn-1-ol 

Relevant articles and documents

Studies on Pd0-catalyzed cyclization of N-3,4-alkadienyl toluenesulfonamides with organic halides: Selective synthesis of 2,3-dihydropyrroles, 1,2,3,6-tetrahydropyrridines, and azetidines

The palladium-catalyzed coupling-cyclization of β-amino allenes with organic halides ranging from aryl halide to 1-alkenyl halide was studied. 2,3-Dihydro-1H-pyrroles were obtained by reaction of 3-substituted-5- unsubstituted-3,4-allenyl amides under conditions A, while the reaction of 5-substituted-3,4-allenyl amides afforded 1,2,5,6-tetrahydropyridines and/or azetidines with high de under conditions B or C. The skeleton and relative configuration of the six-membered products were established by the X-ray diffraction studies of 10ka. Allenyl amide 4q reacted with 1,4-diiodobenzene 6r to afford double cyclization product 15. The structure of its major stereoisomer was also determined by the X-ray diffraction study.