457630-77-2

Upstream product

• 3282-30-2 pivaloyl chloride 
• 488-82-4 D-Arabitol 
• 457630-81-8 (2S,4S)-3-Methylene-1,5-bis-triisopropylsilanyloxy-pentane-2,4-diol 
• 457630-82-9 C₄₀H₆₈O₆Si₂ 
• 457630-80-7 C₁₆H₂₈O₄ 
• 457630-79-4 Bis-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-methanol 

Downstream Products

• 457630-96-5 2,2-dimethyl-propionic acid 2-(4-methoxy-benzyloxy)-3-[1-(4-methoxy-benzyloxy)-2-oxo-ethyl]-but-3-enyl ester 
• 457630-88-5 (2S,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,4-bis-(4-methoxy-benzyloxy)-3,6-dimethylene-9-trimethylsilanyl-non-8-ynal 
• 457630-86-3 2,2-Dimethyl-propionic acid (2S,4S,5S)-5-hydroxy-2,4-bis-(4-methoxy-benzyloxy)-3,6-dimethylene-9-trimethylsilanyl-non-8-ynyl ester 
• 457630-87-4 (2S,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,4-bis-(4-methoxy-benzyloxy)-3,6-dimethylene-9-trimethylsilanyl-non-8-yn-1-ol 
• 457630-97-6 2,2-Dimethyl-propionic acid (2S,4S,5S)-5-(tert-butyl-dimethyl-silanyloxy)-2,4-bis-(4-methoxy-benzyloxy)-3,6-dimethylene-9-trimethylsilanyl-non-8-ynyl ester 

Relevant academic research and scientific papers

Total synthesis of proposed amphidinolide a via a highly selective ring-closing metathesis

(figure presented) key retrosynthetic disconnections a: ring closing metathesis b: indium mediated allylation c: stereoselective anti-aldol d: Mitsunobo esterification e: Stille reaction f-g: chelation controlled add'n A highly convergent synthesis of the