457645-22-6

Upstream product

• 457645-20-4 1-phenyl-1,2-dideoxy-7-O-(phenoxythiocrbonyl)-4,5:6,8-di-O-isopropylidene-D-talo-D-glycero-oct-1-yne 
• 100-39-0 benzyl bromide 
• 457645-21-5 (3aR,4R,5aS,9aR,9bS)-5-benzylidene-2,2,8,8-tetramethylhexahydro-3aH-[1,3]dioxolo[4,5-h][1,3]benzodioxin-4-ol 

Downstream Products

• 457645-24-8 Dithiocarbonic acid O-((3aR,4R,5aS,9aR,9bS)-4-benzyloxy-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-5-yl) ester S-methyl ester 
• 457645-23-7 (3aR,4R,5aR,9aR,9bS)-4-(benzyloxy)-2,2,8,8-tetramethylhexahydro-3aH-[1,3]dioxolo[4,5-h][1,3]benzodioxin-5-ol 
• 457645-25-9 1-O-benzyl-2,3:4,6-di-O-isopropylidene-5a-carba-α-L-gulopyranose 
• 156619-13-5 (1R,2R,3S,4R,5S)-5-Hydroxymethyl-cyclohexane-1,2,3,4-tetraol 

Relevant academic research and scientific papers

Stereodivergent synthesis of carbasugars from D-mannose. Syntheses of 5a-carba-α-D-allose, β-L-talose, and α-L-gulose pentaacetates

A stereodivergent entry to 5a-carba-D- and L-pyranoses from a single precursor is described. The approach is based on the selective deoxygenation of polyoxygenated methylcyclohexane intermediates, readily available from radical cyclization of D-mannose de