458566-05-7

Basic information

• Product Name: (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese
• Synonyms: (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese
• CAS NO: 458566-05-7
• Molecular Weight: 358.66
• Mol File: 458566-05-7.mol

Chemical Properties

• CAS DataBase Reference: (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese(458566-05-7)
• EPA Substance Registry System: (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese(458566-05-7)

Safety Data

• Hazardous Substances Data: 458566-05-7(Hazardous Substances Data)

Upstream product

• 166543-63-1 [tricarbonyl(η(6)-4-chloroanisole)manganese]BF4 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 458566-06-8 [(η5-(1-N(CH2CH2)2O-4-methoxy-6-phenylcyclohexadienyl))Mn(CO)3] 
• 530151-30-5 [(η5-(1-COCH3-4-methoxy-6-phenylcyclohexadienyl))Mn(CO)3] 
• 530151-29-2 (η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese 
• 1010731-53-9 (η5-1-chloro-4-methoxy-2-methyl-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-70-0 (η5-1-chloro-2-(dimethylhydroxymethyl)-4-methoxy-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-71-1 (η5-1-chloro-3-(dimethylhydroxymethyl)-4-methoxy-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-61-9 (η5-1-chloro-4-methoxy-2-iodo-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-62-0 (η5-1-chloro-4-methoxy-3-iodo-6-phenylcyclohexadienyl)Mn(CO)3 
• 898837-73-5 (η5-1-chloro-4-methoxy-2-(trimethylsilyl)-6-phenylcyclohexadienyl)Mn(CO)3 
• 898837-81-5 (η5-1-chloro-4-methoxy-3-(trimethylsilyl)-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-55-1 (η5-1-chloro-4-methoxy-2-(CO2Et)-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-56-2 (η5-1-chloro-4-methoxy-3-(CO2Et)-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010811-20-7 (η5-1-chloro-2-(phenylhydroxymethyl)-4-methoxy-6-phenylcyclohexadienyl)Mn(CO)3 
• 1010731-69-7 (η5-1-chloro-3-(phenylhydroxymethyl)-4-methoxy-6-phenylcyclohexadienyl)Mn(CO)3 

Relevant articles and documents

New access to (η5-cyclohexadienyl)Mn(CO)3 and cationic (η6-arene)Mn(CO)3 complexes by Suzuki-Miyaura reaction

First Suzuki-Miyaura coupling reactions applied to (η5- chloro-cyclohexadienyl)Mn(CO)3 complexes are described and lead to the syntheses of (η5-aryl-cyclohexadienyl)Mn(CO)3 and of cationic (η6-arene)M

η6-(Arene)tricarbonylchromium and manganese complexes linked to 2′-deoxyuridine

Synthesis of η6-(arene)tricarbonylchromium and manganese complexes linked to 2′-deoxyuridine via a triple-bond spacer is reported using palladium-catalyzed reactions of alkynes with halogeno derivatives, and their antiviral activity in cell-based assays studied.

Palladium-catalyzed chloride substitution of η5-(Chlorocyclohexadienyl)Mn(CO)3 complexes: An access to novel η6-(Arene)Mn(CO)3+ cations

Functionalization of η5-(chlorocyclohexadienyl)Mn(CO)3 complexes was achieved by palladium-catalyzed reactions using Pd2(dba)3 in the presence of AsPh3. Arylation, carbonylation, and substitution by a