45860-18-2Relevant articles and documents
Deoxygenation of nitrosoarene by N-heterocyclic carbene (NHC): an elusive Breslow-type intermediate bridging carbene and nitrene
B. S., Anju,Bhattacharjee, Rameswar,Gupta, Shourya,Ahammad, Soniya,Datta, Ayan,Kundu, Subrata
, p. 12166 - 12169 (2020)
N-Heterocyclic carbene (NHC) activates and deoxygenates nitrosoarene (ArNO) to afford arylnitrene (ArN), thereby portraying a fundamental route connecting two 6e?species. A combination of spectroscopic and computational studies suggests that th