460343-69-5Relevant academic research and scientific papers
Diastereoselective cycloreductions and cycloadditions catalyzed by Co(dpm)2-silane (dpm = 2,2,6,6-tetramethylheptane-3,5-dionate): Mechanism and partitioning of hydrometallative versus anion radical pathways
Wang, Long-Cheng,Jang, Hye-Young,Roh, Yeonsuk,Lynch, Vincent,Schultz, Arthur J.,Wang, Xiaoping,Krische, Michael J.
, p. 9448 - 9453 (2002)
In the presence of phenylsilane and 5 mol % cobalt(II) bis(2,2,6,6-tetramethylheptane-3,5-dionate), aryl-substituted monoenone monoaldehydes and bis(enones) undergo reductive cyclization to afford synaldol and anti-Michael products, respectively. For both
