461383-60-8Relevant academic research and scientific papers
Regioselective 1,2,3-bisazfulleroid: Doubly N-bridged bisimino-PCBMs for polymer solar cells
Kim, Boram,Lee, Junghoon,Seo, Jung Hwa,Wudl, Fred,Park, Sung Heum,Yang, Changduk
, p. 22958 - 22963 (2013/01/15)
The direct bisaddition of methyl 5-azido-5-phenylpentanoate to C60takes place in the two neighboring pentagon-hexagon junctions of the same five-membered ring, yielding a regioselective bisazfulleroid, namely bisimino-PCBM. Because of its open
Intramolecular Cyclization of Acyl Radicals onto the Azido Group: A New Radical Approach to Cyclized Lactams
Benati, Luisa,Leardini, Rino,Minozzi, Matteo,Nanni, Daniele,Spagnolo, Piero,Strazzari, Samantha,Zanardi, Giuseppe
, p. 3079 - 3081 (2007/10/03)
(Equation Presented) Reagents: i, Bu3SnH/AlBN; ii, (TMS)3SiH/AlBN. Aryl- and alkyl-derived azidoacyl radicals, generated from thiolesters by intramolecular homolytic substitution at the sulfur, can undergo five- and six-membered cyclization onto the azido moiety to give cyclized lactams.
