46298-13-9Relevant academic research and scientific papers
Copper-Catalyzed three- Five- or seven-Component coupling reactions: The selective synthesis of cyanomethylamines, N,N-bis(cyanomethyl)amines and N,N'-bis(cyanomethyl)methylenediamines based on a strecker-type synthesis
Sakai, Norio,Takahashi, Nobuaki,Inoda, Daiki,Ikeda, Reiko,Konakahara, Takeo
, p. 12488 - 12499 (2013/11/06)
We have demonstrated that a cooperative catalytic system comprised of CuCl and Cu(OTf)2 could be used to effectively catalyse the three-, five- and seven-component coupling reactions of aliphatic or aromatic amines, formaldehyde, and trimethylsilyl cyanide (TMSCN), and selectively produce in good yields the corresponding cyanomethylamines, N,N-bis(cyanomethyl)amines and N,N'-bis(cyanomethyl)methylenediamines.
Graphene oxide and rose bengal: Oxidative C-H functionalisation of tertiary amines using visible light
Pan, Yuanhang,Wang, Shuai,Kee, Choon Wee,Dubuisson, Emilie,Yang, Yuanyong,Loh, Kian Ping,Tan, Choon-Hong
supporting information; experimental part, p. 3341 - 3344 (2012/01/06)
Visible light induced oxidative C-H functionalisation of tertiary amines catalysed by the combination of graphene oxide and Rose Bengal was developed. This reaction avoids the use of stoichiometric amounts of peroxy compounds as terminal oxidants. This re
