464191-09-1

Basic information

• Product Name: trans-[Mo₂(acetate)2(N,N'-di(2-methoxyphenyl)formamidinate)2]
• CAS NO: 464191-09-1
• Molecular Weight: 820.562
• Mol File: 464191-09-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-[Mo₂(acetate)2(N,N'-di(2-methoxyphenyl)formamidinate)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[Mo₂(acetate)2(N,N'-di(2-methoxyphenyl)formamidinate)2](464191-09-1)
• EPA Substance Registry System: trans-[Mo₂(acetate)2(N,N'-di(2-methoxyphenyl)formamidinate)2](464191-09-1)

Safety Data

• Hazardous Substances Data: 464191-09-1(Hazardous Substances Data)

Upstream product

• 14221-06-8 tetrakis(acetato)dimolybdenum(II) 
• 68012-05-5 N,N'-bis(2-methoxyphenyl)formamidine 

Downstream Products

• 685834-81-5 trans-[Mo₂(acetate)(N,N'-di(6-methyl-2-pyridyl)formamidinate)2(N,N'-di(2-methoxyphenyl)formamidinate)] 
• 685834-82-6 trans-[Mo₂(N,N'-di(6-methyl-2-pyridyl)formamidinate)2(N,N'-di(2-methoxyphenyl)formamidinate)2] 
• 685834-80-4 trans-[Mo₂(acetate)(N,N'-di(6-methyl-2-pyridyl)formamidinate)(N,N'-di(2-methoxyphenyl)formamidinate)2] 
• 685834-79-1 trans-[Mo₂(acetate)(N,N'-di(pyrimidyl)formamidinate)(N,N'-di(2-methoxyphenyl)formamidinate)2] 

Relevant articles and documents

Dimolybdenum complexes with mixed formamidinate ligands

A series of dimolybdenum complexes containing mixed formamidinate ligand are discussed. The reactions of trans-Mo2(O2CCH 3)2(o-DMophF)2 [o-HDMophF = N,N′-di(2-methoxyphenyl)formamidine] with N,N′-di(2-pyridyl) formamidine (HDpyF), N,N′-di(2-pyrimidyl)formamidine (HDpmF) and N,N′-di(6-methyl-2-pyridyl)formamidine (HDMepyF), in refluxing CH 2Cl2 afforded the complexes, trans-Mo2(O 2CCH3)(DpyF)(o-DMophF)2 (1), trans-Mo 2(O2CCH3)(DpmF)(o-DMophF)2 (2), and trans-Mo2(O2CCH3)(DMepyF)(o-DMophF) 2 (3), respectively. The o-DMophF- and DMepyF- ligands in these complexes adopt the s-cis, s-trans conformation, resulting in Mo-O short distances [2.889 (3) and 2.861(2) ? for 1; 2.880(3) and 3.024(4) ? for 2], while the DpyF- ligand adopts the s-cis, s-trans conformation, resulting in a Mo-N [3.208(4) ?] and a Mo-H [2.90 (3) ?] short distances. The reactions of trans-Mo2(O 2CCH3)2(o-DMophF)2 with HDMepyF in CH3CN gave complexes 3, trans-Mo2(O2CCH 3)(DMepyF)2(o-DMophF) (4), and trans-Mo 2(DMepyF)2(o-DMophF)2 (5). The o-DMophF - ligands in 4 and 5 adopt the s-cis, s-cis conformation while DMepyF- assumes an s-cis, s-trans conformation. Complexes 1-5 are the first dimolybdenum complexes containing mixed formamidinate ligands.