465545-17-9Relevant academic research and scientific papers
Stereoselectivity of intramolecular SN′ cyclizations of alkyllithium reagents on methoxy alkenes
La Cruz, Thomas E.,Rychnovsky, Scott D.
, p. 1068 - 1073 (2007/10/03)
The cyclization of alkyllithium reagents onto methoxy alkenes has been investigated. The alkyllithium reagent was generated by reductive lithiation of an alkyl nitrile. In an unbiased substrate, a methoxy leaving group attached to a stereogenic secondary
Empirical model for the molar rotations of syn-2,2-dimethyl-1,3-dioxanes.
Anderson, Christopher D,Rychnovsky, Scott D
, p. 3075 - 3078 (2007/10/03)
[structure: see text] A useful method for the prediction of molar rotation ([Phi]) of syn-2,2-dimethyl-1,3-dioxanes (acetonides) is described. A series of acetonides were prepared by standard methods. A simple additive relationship between the substituent
