4663-81-4

Basic information

• Product Name: Bismuth, dihydroxytriphenyl-
• CAS NO: 4663-81-4
• Molecular Formula: C18H17BiO2
• Molecular Weight: 474.312
• Mol File: 4663-81-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Bismuth, dihydroxytriphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Bismuth, dihydroxytriphenyl-(4663-81-4)
• EPA Substance Registry System: Bismuth, dihydroxytriphenyl-(4663-81-4)

Safety Data

• Hazardous Substances Data: 4663-81-4(Hazardous Substances Data)

Upstream product

• 265662-35-9 triphenylbismuth bis(2,4-dimethylbenzenesulfonate) 
• 7732-18-5 water 
• 28899-97-0 triphenylbismuth(V) diacetate 
• 507233-69-4 triphenyl bismuth ⁽²⁺⁾; dichloride 
• 20667-12-3 silver(l) oxide 

Downstream Products

• 603-33-8 triphenylbismuthane 
• 66214-57-1 (C₆H₅)3Bi(OH)Cl 
• 507233-69-4 triphenyl bismuth ⁽²⁺⁾; dichloride 
• 1304-76-3 bismuth(III) oxide 

Relevant articles and documents

Diverse structures and remarkable oxidizing ability of triarylbismuthane oxides. Comparative study on the structure and reactivity of a series of triarylpnictogen oxides

A systematic series of triarylbismuthane oxides was prepared in order to disclose their structure and reactivity, which have been compared with those of lighter pnictogen counterparts. X-ray crystallographic analysis of tris(2-methoxyphenyl)bismuthane oxide and tris(2-methoxyphenyl)stibane oxide revealed that they exist as dimers with a flat bis(a-oxo) ring, implying that the polarized Bi+-O- and Sb+-O- bonds aggregate to attain electrostatic stabilization. In sharp contrast to their phosphorus, arsenic, and antimony counterparts, triarylbismuthane oxides are thermally unstable and possess a high oxidizing ability. In particular, the bismuthane oxides bearing ortho-substituted aryl ligands oxidized primary and secondary alcohols to aldehydes and ketones, respectively, with high efficiency under mild conditions.