467224-89-1Relevant academic research and scientific papers
Diastereoselectivity in the epoxidation of γ-hydroxy α,β-unsaturated esters: Temperature and solvent effect
Rodríguez, Santiago,Vidal, Alberto,Monroig, Juan J.,González, Florenci V.
, p. 5359 - 5361 (2004)
The diastereoselectivity in the nucleophilic epoxidation of γ-hydroxy α,β-unsaturated compounds using lithium-tert-butylperoxide is highly dependent on the reaction solvent but not influenced by the temperature. The free hydroxyl is key for stereoselection.
Diastereoselective synthesis of γ-hydroxy α,β-epoxyesters and their conversion into β-hydroxy α-sulfenyl γ-butyrolactones
Rodríguez, Santiago,Kneeteman, María,Izquierdo, Javier,López, Irakusne,González, Florenci?V.,Peris, Gabriel
, p. 11112 - 11123 (2007/10/03)
The diastereoselectivity of the nucleophilic epoxidation of γ-hydroxy-α,β-unsaturated esters has been studied. The γ-hydroxy-α,β-unsaturated esters were obtained through treatment of ethyl (E)-4-oxo-2-butenoate with the corresponding Grignard reagent and
