468078-68-4Relevant academic research and scientific papers
Efficient preparation of polysubstituted naphthyl phenyl and dinaphthyl ketones from naphthalenic esters by anionic homo-Fries rearrangement
Piettre, Arnaud,Massardier, Christine,Chevenier, Emmanuel,Gimbert, Yves,Greene, Andrew E.
, p. 2086 - 2088 (2002)
The anionic homo-Fries rearrangement of naphthalenic esters can be effected in good yield to provide regiocontrolled access to complex diaryl ketones.
Synthetic Approach to Hypoxyxylerone, Novel Inhibitor of Topoisomerase I
Piettre, Arnaud,Chevenier, Emmanuel,Massardier, Christine,Gimbert, Yves,Greene, Andrew E.
, p. 3139 - 3142 (2007/10/03)
(Equation Presented) A potential route to the topoisomerase I inhibitor hypoxyxylerone is demonstrated by a highly convergent synthesis of the penta(O-methyl) derivative. The key step in the approach is an anionic homo-Fries rearrangement, little used to
