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468082-88-4

Ru(H)(Cl)(CO)(DCPB)(PPh3) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 468082-88-4 Structure

  • Basic information

    1. Product Name: Ru(H)(Cl)(CO)(DCPB)(PPh3)
    2. Synonyms: Ru(H)(Cl)(CO)(DCPB)(PPh3)
    3. CAS NO:468082-88-4
    4. Molecular Formula:
    5. Molecular Weight: 878.501
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 468082-88-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Ru(H)(Cl)(CO)(DCPB)(PPh3)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Ru(H)(Cl)(CO)(DCPB)(PPh3)(468082-88-4)
    11. EPA Substance Registry System: Ru(H)(Cl)(CO)(DCPB)(PPh3)(468082-88-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 468082-88-4(Hazardous Substances Data)

468082-88-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 468082-88-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,6,8,0,8 and 2 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 468082-88:
(8*4)+(7*6)+(6*8)+(5*0)+(4*8)+(3*2)+(2*8)+(1*8)=184
184 % 10 = 4
So 468082-88-4 is a valid CAS Registry Number.

468082-88-4Downstream Products

468082-88-4Relevant articles and documents

Ruthenium-Catalyzed Coupling Reactions of CO2 with C2H4 and Hydrosilanes towards Silyl Esters

Kunihiro, Kana,Heyte, Svetlana,Paul, Sébastien,Roisnel, Thierry,Carpentier, Jean-Fran?ois,Kirillov, Evgueni

, p. 3997 - 4003 (2021)

A series of in situ-prepared catalytic systems incorporating RuII precursors and bidentate phosphine ligands has been probed in the reductive carboxylation of ethylene in the presence of triethylsilane as reductant. The catalytic production of propionate and acrylate silyl esters was evidenced by high-throughput screening (HTS) and implemented in batch reactor techniques. The most promising catalyst systems identified were made of Ru(H)(Cl)(CO)(PPh3)3 and 1,4-bis(dicyclohexylphosphino)butane (DCPB) or 1,1’-ferrocene-diyl-bis(cyclohexylphosphine) (DCPF). A marked influence of water on the acrylate/propionate selectivity was noted. Turnover numbers [mol mol(Ru)?1] up to 16 for acrylate and up to 68 for propionate were reached under relatively mild conditions (20 bar, 100 °C, 0.5 mol % Ru, 40 mol % H2O vs. HSiEt3). Possible mechanisms are discussed.

Reactions of hydrogen with ruthenium and osmium complexes containing tridentate ligands Cy2PCH2CH(CH2) 2PCy2 and 2,6-(Ph2PCH2) 2C6H3

Liu, Sheng Hua,Lo, Shu Tak,Wen, Ting Bin,Williams, Ian D.,Zhou, Zhong Yuan,Lau, Chak Po,Jia, Guochen

, p. 122 - 130 (2008/10/08)

Reaction of cis-1,4-dichlorobut-2-ene with dicyclohexylphosphine in the presence of KI in acetone produces [cis-Cy2PHCH2CH= CHCH2PHCy2]I2, which is converted to cis-Cy2PCH2CH=CHC

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