4702-99-2

Upstream product

• 92553-88-3 2-(benzamidooxy)-2-phenylacetic acid 

Downstream Products

• 4585-66-4 (+/-)-α-<2-Hydroxy-(1)naphthylideniminooxy>-phenylessigsaeure 
• 4703-03-1 2-((((benzyloxy)carbonyl)amino)oxy)-2-phenylacetic acid 
• 4585-60-8 (5-chloro-2-hydroxy-benzylideneaminooxy)-phenyl-acetic acid 
• 4585-53-9 (2-bromo-benzylideneaminooxy)-phenyl-acetic acid 
• 4585-62-0 isopropylideneaminooxy-phenyl-acetic acid 
• 4585-52-8 (2-fluoro-benzylideneaminooxy)-phenyl-acetic acid 
• 4585-51-7 benzylideneaminooxy-phenyl-acetic acid 
• 4585-63-1 cyclohexylideneaminooxy-phenyl-acetic acid 
• 5821-01-2 α-Ureido-oxy-phenylessigsaeure 
• 5766-88-1 α-Aminooxy-phenylessigsaeure-aethylester 
• 4585-65-3 benzhydrylideneaminooxy-phenyl-acetic acid 

Relevant academic research and scientific papers

Iminyl-Radicals by Oxidation of α-Imino-oxy Acids: Photoredox-Neutral Alkene Carboimination for the Synthesis of Pyrrolines

The visible-light-promoted decarboxylation of α-imino-oxy propionic acids for the generation of iminyl radicals has been accomplished through the use of Ir(dFCF3ppy)2(dtbbpy)PF6 as a photoredox catalyst. Different from visible-light-promoted homolysis and single-electron reduction of oxime derivatives, this strategy provides a novel catalytic cycle for alkene carboimination through a sequence comprising N-radical generation, iminyl radical cyclization, intermolecular conjugate addition to a Michael acceptor, and single-electron reduction to afford various pyrroline derivatives in an overall redox-neutral process. The indolizidine alkaloid skeleton could be easily constructed from a pyrroline derivative prepared by this synthetic method.