470475-08-2

Upstream product

• 385441-42-9 Ru(η6-C6H6)(η-(C4H9N)2CC6H5)Cl 
• 75-05-8 acetonitrile 

Downstream Products

• 470475-12-8 Ru(N(C(CH₃)3)C(C₆H₅)N(C(CH₃)3))(CH₃CN)2(C₅H₅N)2⁽¹⁺⁾*PF₆^(1-)=[Ru(C₄H₉NCC₆H₅NC₄H₉)(CH₃CN)2(C₅H₅N)2]PF₆ 
• 470475-16-2 Ru(N(C(CH₃)3)C(C₆H₅)N(C(CH₃)3))(CH₃CN)2(CNC(CH₃)3)2⁽¹⁺⁾*PF₆^(1-)=[Ru(C₄H₉NCC₆H₅NC₄H₉)(CH₃CN)2(CNC₄H₉)2]PF₆ 
• 470475-10-6 Ru(N(C(CH₃)3)C(C₆H₅)N(C(CH₃)3))(CH₃CN)2(C₅H₄NC₅H₄N)⁽¹⁺⁾*PF₆^(1-)=[Ru(C₄H₉NCC₆H₅NC₄H₉)(CH₃CN)2(C₅H₄NC₅H₄N)]PF₆ 
• 470475-14-0 Ru(N(C(CH₃)3)C(C₆H₅)N(C(CH₃)3))(CH₃CN)3(P(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=[Ru(C₄H₉NCC₆H₅NC₄H₉)(CH₃CN)3P(C₆H₅)3]PF₆ 

Relevant academic research and scientific papers

Access to novel ruthenium-amidinate complexes, (η6-arene)Ru(η2-amidinate)X and [Ru(η2-amidinate)(MeCN)4]+PF6 - by photochemical displacement of the benzene ligand in (η6-C6H6)Ru(η2-amidinate)X

A study of novel ruthenium-amidinate complexes was carried out by photochemical displacement of benzene ligand. The complex 5 also reacted with pyridine to give a bispyridine complex. The acetonitrile ligands of 5 are easily replaceable by other σ-donor ligands (L) such as pyridines, phosphines, and isocyanides.