4705-06-0

Basic information

• Product Name: (1R,4R)-4-Isopropyl-2-cyclohexen-1-ol
• Synonyms: (+)-cis-Cryptol;(1R,4R)-4-Isopropyl-2-cyclohexen-1-ol
• CAS NO: 4705-06-0
• Molecular Formula: C₉H₁₆O
• Molecular Weight: 0
• Mol File: 4705-06-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (1R,4R)-4-Isopropyl-2-cyclohexen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R)-4-Isopropyl-2-cyclohexen-1-ol(4705-06-0)
• EPA Substance Registry System: (1R,4R)-4-Isopropyl-2-cyclohexen-1-ol(4705-06-0)

Safety Data

• Hazardous Substances Data: 4705-06-0(Hazardous Substances Data)

Upstream product

• 555-31-7 aluminum isopropoxide 
• 2158-59-0 cryptone 
• 2158-59-0 (R)-(-)-cryptone 
• 66031-65-0 (+)-O-(3.5-dinitro-benzoyl)-cis-cryptol 

Downstream Products

• 64180-94-5 trans-o-menth-2-ene 
• 64180-94-5 cis-o-menth-2-ene 
• 1124-26-1 (+/-)-(3R,6S)-3-isopropyl-6-methyl-1-cyclohexene 
• 1124-26-1 (+/-)-(3R,6R)-3-isopropyl-6-methyl-1-cyclohexene 
• 66031-65-0 (+)-O-(3.5-dinitro-benzoyl)-cis-cryptol 
• 83670-70-6 Acetic acid (1S,4R)-4-isopropyl-cyclohex-2-enyl ester 
• 15890-36-5 trans-4-isopropylcyclohexanol 

Relevant articles and documents

Asymmetric total synthesis and X-ray crystal structure of the cytotoxic marine diterpene (+)-vigulariol

(Figure Presented) A crystal from the China sea: The asymmetric total synthesis of (+)-vigulariol (see picture: red O, blue C, white H) has been accomplished in eight linear steps starting from (R)-cryptone, which is readily available from eucalyptus oil. Key steps involve an asymmetric homoaldol reaction of chiral allyl carbamates and THF cyclocondensation. Ring-closing metathesis led to the tricyclic framework of the cladiellin diterpenes.