4711-72-2

Basic information

• Product Name: 2,4-Pentadienoyl chloride,5-(1,3-benzodioxol- 5-yl)-
• Synonyms: 5-Benzo[1,3]dioxol-5-yl-penta-2,4-dienoylchlorid;5-benzo[1,3]dioxol-5-yl-penta-2,4-dienoyl chloride;5t-Benzo[1,3]dioxol-5-yl-penta-2t,4-dienoylchlorid;SCT-08;(2E,4E)-5-Benzo[1,3]dioxol-5-yl-penta-2,4-dienoyl chloride;Piperinsaeure-chlorid;5t-benzo[1,3]dioxol-5-yl-penta-2t,4-dienoyl chloride
• CAS NO: 4711-72-2
• Molecular Formula: C12H9ClO3
• Molecular Weight: 236.655
• Mol File: 4711-72-2.mol

Chemical Properties

• CAS DataBase Reference: 2,4-Pentadienoyl chloride,5-(1,3-benzodioxol- 5-yl)- (CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Pentadienoyl chloride,5-(1,3-benzodioxol- 5-yl)- (4711-72-2)
• EPA Substance Registry System: 2,4-Pentadienoyl chloride,5-(1,3-benzodioxol- 5-yl)- (4711-72-2)

Safety Data

• Hazardous Substances Data: 4711-72-2(Hazardous Substances Data)

Usage

Type of compound

Acyl chloride

Contains

2,4-pentadienoyl group and 5-(1,3-benzodioxol-5-yl) substituent

Usage

Organic synthesis reactions, building block for pharmaceuticals, agrochemicals, and other fine chemicals

Safety

Flammable, should be handled with care in a well-ventilated environment.

Upstream product

• 6190-46-1 methyl (2E,4E)-5-(benzo[d][1,3]dioxol-5-yl)penta-2,4-dienoate 

Downstream Products

• 94-62-2 Piperine 
• 5950-12-9 piperlonguminine 
• 263744-11-2 (2E,4E)-5-(benzo[d][1,3]dioxol-5-yl)-N-cyclohexylpenta-2,4-dienamide 
• 26163-80-4 (2E,4E)-5-(benzo[d][1,3]dioxol-5-yl)-1-morpholinopenta-2,4-dien-1-one 
• 1029101-14-1 C₂₅H₂₀N₃O₂S⁽¹⁺⁾*Cl^(1-) 
• 1374124-00-1 C₁₅H₂₁NO₃ 
• 6091-43-6 all-trans-5-(3,4-Methylendioxyphenyl)-2,4-pentadiensaeureethylester 
• 6190-46-1 methyl (2E,4E)-5-(benzo[d][1,3]dioxol-5-yl)penta-2,4-dienoate 

Relevant articles and documents

Substituent Effects on Carbon-13 NMR Chemical Shifts of Side-chain Carbons in 5-Aryl-2E,4E-pentadienoic Acid Derivatives

The 13C NMR spectra of two series of 5-aryl-2E,4E-pentadienoic acid derivatives, viz. the methyl esters and piperidides have been determined.The chemical shifts of C-2 and C-4 show very good correlations with the Hammett ?+-constants for all the substituents investigated, except for the para-nitro group which is capable of excerting a strong -R effect.A possible explanation for this has been advanced.Hammett correlations between substituents and the chemical shifts of both C-3 and C-5 carbons using ?0 parameters are less satisfactory.A reverse chemical shift effect has been observed for these two centres.