471930-32-2Relevant academic research and scientific papers
3-silylated cyclohexa-1,4-dienes as precursors for gaseous hydrosilanes: The B(C6F5)3-catalyzed transfer hydrosilylation of alkenes
Simonneau, Antoine,Oestreich, Martin
, (2013)
Set Me3SiH free! The strong Lewis acid B(C6F 5)3 catalyzes the release of hydrosilanes from 3-silylated cyclohexa-1,4-dienes with concomitant formation of benzene. Subsequent B(C 6F5)3
Development of the [3 + 2] annulations of cyclohexenylsilanes and chlorosulfonyl isocyanate: Application to the total synthesis of (±)-peduncularine
Roberson, Claudia W.,Woerpel
, p. 11342 - 11348 (2007/10/03)
The synthesis of (±)-peduncularine was accomplished using the [3 + 2] annulation of an allylic silane with chlorosulfonyl isocyanate to assemble the bicyclic core of the alkaloid. The stereochemistry of the annulation product was employed to control the i
