4723-24-4Relevant academic research and scientific papers
Synthesis and reactivity of chiral pentavalent bismuth derivatives
Finet,Fedorov
, p. 1488 - 1495 (2007/10/03)
Eight new pentavalent organobismuth derivatives were synthesized by the reactions of triphenylbismuth or phenyl-2,2"-biphenylenebismuth with chiral (1R)-(-)-camphor-10-sulfonic, (-)-menthyloxyacetic, or (R)-3-phenylbutyric acids. Enantioselective C-arylat
Observations on the Cleavage of the Bismuth-carbon bond in BiV Compounds: a New Arylation Reaction
Barton, Derek H. R.,Lester, David J.,Motherwell, William B.,Papoula, M. Teresa Barros
, p. 246 - 247 (2007/10/02)
Further examples of the selectivity of pentavalent triaryl-organobismuth oxidants are presented; deuterium labelling studies have established that the mechanism of oxidation of allylic alcohols by these reagents involves, to some extent, cleavage of the bismuth-aryl bond; several reactions involving the synthetically useful transfer of an aryl group from bismuth to nitrogen and to carbon are described.
