473-10-9

Usage

Uses

Used in Fragrance Industry:
Carissone is used as a fragrance ingredient for its strong, sweet, and floral scent, enhancing the aroma profiles of perfumes and other scented products.
Used in Pharmaceutical Industry:
Although not explicitly stated in the materials, the potential applications of Carissone in the pharmaceutical industry could be attributed to its chemical properties, which may be harnessed for developing new drugs or medicinal compounds.
Used in Agrochemical Industry:
Similarly, the potential of Carissone in the agrochemical industry might be due to its chemical structure, which could be utilized in the development of pesticides, herbicides, or other agricultural chemicals.

Upstream product

• 473-16-5 r-eudesmol 
• 15051-79-3 3-hydroxy-γ-eudesmol 
• 163276-51-5 11-hydroxy-4-eudesmadien-3-one 
• 51911-69-4 (1S,3S,6R)-3,7,7-Trimethyl-3-(3-oxo-pentyl)-bicyclo[4.1.0]heptan-2-one 
• 69427-76-5 eudesm-4-ene-3β,11-diol 
• 83093-41-8 (S)-7-(1,2-Dihydroxy-1-methyl-ethyl)-1,4a-dimethyl-4,4a,5,6-tetrahydro-3H-naphthalen-2-one 
• 83093-40-7 (S)-7-Isopropenyl-1,4a-dimethyl-4,4a,5,6-tetrahydro-3H-naphthalen-2-one 
• 83093-44-1 Toluene-4-sulfonic acid 2-((2R,4aS)-4a,8-dimethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydro-naphthalen-2-yl)-2-hydroxy-propyl ester 
• 83093-34-9 (4aS,7R,8S)-8-Bromo-7-hydroxy-7-isopropyl-1,4a-dimethyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one 
• 23665-63-6 β-cyperone 
• 56423-84-8 11,12-dihydroxyeudesm-4-en-3-one 
• 473-08-5 eudesma-4,11-dien-3-one 
• 263860-43-1 11,12-Oxido-α-cyperone 

Downstream Products

• 473-16-5 r-eudesmol 

Relevant academic research and scientific papers

Catalytic enantioselective approach to the eudesmane sesquiterpenoids: Total synthesis of (+)-carissone

(Chemical Equation Presented) A catalytic enantioselective approach to the eudesmane sesquiterpenoids is reported. The strategic use of a palladium-catalyzed enantioselective alkylation of vinylogous ester substrates forged the C(10) all-carbon quaternary

Stereoselective total synthesis of (-)-α-eudesmol, a P/Q-type calcium channel blocker

Practical and stereoselective total synthesis of (-)-αeudesmol 1, a P/Q-type calcium channel blocker, has been achieved with the key step being a cyclopropane ring opening accompanying introduction of a hydroxyl group. (+)-Carissone is used as a key intermediate.

FIRST TOTAL SYNTHESIS OF (-)-DEHYDROCARISSONE

The first synthesis of (-)-dehydrocarissone (1) has been described, employing the dehydrogenation with DDQ as the key step.

STRESS COMPOUNDS IN THE LEAVES OF NICOTIANA UNDULATA INDUCED BY TMV INOCULATION

In leaves of Nicotiana undulata inoculated with TVM, 19 sesquiterpenoids were detected as stress compounds.Among them, dehydrocarissone, capsidiol 3-acetate, aubergenone, 4-epi-aubergenone, trans-dihydrocarissone, 1,2-dehydro-α-cyperone and 3-epi-3-hydroxysolavetivone are novel tobacco stress compounds.Key Word Index - Nicotiana undulata; Solanaceae; tobacco; sesquiterpenoid; stress compounds.

Allylic Oxidation of Δ2-Santenolide Using Dipyridylchromium Trioxide and Selenium Dioxide

Allylic oxidations of Δ2-santenolide (1) with dipyridylchromium trioxide and selenium dioxide are described.With the former reagent, the products are 1-oxo-Δ2-santenolide (2), 3-oxo-Δ1-santenolide (7) and 2-oxo-Δ3-santenolide (9), while with the latter reagent the product is 1α-hydroxy-Δ2-santenolide (3).The allylic oxidation of α-eudesmol (10) with dipyridylchromium trioxide gives in one-step, as expected, the naturally ocurring α,β-unsaturated ketone carissone (11).