47304-99-4

Basic information

• Product Name: Bis(2-naphthalenylMethyl)aMine
• Synonyms: Bis(2-naphthalenylMethyl)aMine;bis(naphthalen-2-ylmethyl)amine
• CAS NO: 47304-99-4
• Molecular Formula: C₂₂H₁₉N
• Molecular Weight: 297.39296
• Mol File: 47304-99-4.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bis(2-naphthalenylMethyl)aMine(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(2-naphthalenylMethyl)aMine(47304-99-4)
• EPA Substance Registry System: Bis(2-naphthalenylMethyl)aMine(47304-99-4)

Safety Data

• Hazardous Substances Data: 47304-99-4(Hazardous Substances Data)

Usage

Uses

Bis(2-naphthalenylmethyl)amine is used in preparation of primary amines via nitrogen-doped carbon supported cobalt-nanocatalyzed reductive amination of aldehydes.

Upstream product

• 1592-38-7 2-Naphthalenemethanol 
• 2018-90-8 naphthalen-2-ylmethylamine 
• 2038-57-5 3-Phenylpropan-1-amine 
• 613-46-7 2-naphthalenecarbonitrile 

Downstream Products

• 6852-58-0 N-benzylidene tert-butylamine 
• 1253527-47-7 (E)-N'-(cyclohexyloxy)-N,N-bis(naphthalen-2-ylmethyl)-1-nitromethanimidamide 

Relevant articles and documents

N-Alkylation of Aqueous Ammonia with Alcohols Leading to Primary Amines Catalyzed by Water-Soluble N-Heterocyclic Carbene Complexes of Iridium

A new catalytic system for the N-monoalkylation of aqueous ammonia with a variety of alcohols was developed. Water-soluble dicationic complexes of iridium bearing N-heterocyclic carbene and diammine ligands exhibited high catalytic activity for this type of reaction on the basis of hydrogen-transfer processes without generating harmful or wasteful byproducts. Various primary amines were efficiently synthesized by using safe, inexpensive, and easily handled aqueous ammonia as a nitrogen source. For example, the reaction of 1-(4-methylphenyl)ethanol with aqueous ammonia in the presence of a water-soluble N-heterocyclic carbene complex of iridium at 150 °C for 40 h gave 1-(4-methylphenyl)ethylamine in 83 % yield.