473536-55-9

Upstream product

• 5056-07-5 (S)-methyl p-tolyl sulfoxide 
• 473536-52-6 (SS)-4-hydroxy-4-[(p-tolylsulfinyl)methyl]-cyclohexa-2,5-dienone 
• 473536-53-7 [4R,5R,SS]-4-hydroxy-5-methyl-4-[(p-tolylsulfinyl)methyl]-2-cyclohexen-1-one 
• 473536-54-8 (4R,5R)-4-hydroxy-5-methyl-4-[(p-tolylsulfonyl)methyl]-2-cyclohexen-1-one 

Downstream Products

• 473536-56-0 (1R,4S,6R)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-1-[(p-tolylsulfonyl)methyl]-2-cyclohexen-1-ol 
• 473536-57-1 (4S,6R)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-2-cyclohexen-1-one 
• 473536-58-2 (4S,6R)-2-bromo-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-2-cyclohexen-1-one 
• 473536-51-5 (1S,4S,6R)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-2-vinyl-2-cyclohexen-1-yl-isobutyrate 
• 473536-60-6 Isobutyric acid (1S,4S,6R)-2-bromo-4-(tert-butyl-dimethyl-silanyloxy)-6-methyl-cyclohex-2-enyl ester 
• 473536-59-3 (1S,4S,6R)-2-Bromo-4-(tert-butyl-dimethyl-silanyloxy)-6-methyl-cyclohex-2-enol 

Relevant academic research and scientific papers

Asymmetric synthesis of rubiginones A2 and C2 and their 11-methoxy regioisomers

Convergent enantioselective syntheses of angucyclinone-type natural products rubiginones A2 (2) and C2 (1) and their 11-methoxy regioisomers 3a and 3b have been achieved by using two domino processes from a common enantiomerically pu

Enantioselective synthesis of (+)- and (-)-dihydroepiepoformin and (+)-epiepoformin

(Chemical Equation Presented) The enantioselective synthesis of both enantiomers of dihydroepiepoformin (1) and (+)-epiepoformin (2) was achieved from (p-tolylsulfinyl)-methyl-p-quinols (SR)- or (SS)-3 and (4R,SR)-4, respectively. Key features include the

Enantioselective total synthesis of angucyclinone-type antibiotics rubiginones A2 and C2

The tetracyclic skeleton of C4-oxygenated angucyclinone-type antibiotics rubiginones A2 ((+)-3) and C2 ((-)-4) is constructed by Diels-Alder reaction of a racemic sulfinyl-substituted methyl juglone and the enantiopure vinyl cyclohex