473536-59-3

Upstream product

• 473536-56-0 (1R,4S,6R)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-1-[(p-tolylsulfonyl)methyl]-2-cyclohexen-1-ol 
• 473536-55-9 (1R,4S,6R)-6-methyl-1-[(p-tolylsulfonyl)methyl]-2-cyclohexen-1,4-diol 
• 473536-54-8 (4R,5R)-4-hydroxy-5-methyl-4-[(p-tolylsulfonyl)methyl]-2-cyclohexen-1-one 
• 473536-53-7 [4R,5R,SS]-4-hydroxy-5-methyl-4-[(p-tolylsulfinyl)methyl]-2-cyclohexen-1-one 
• 473536-57-1 (4S,6R)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-2-cyclohexen-1-one 

Downstream Products

• 473536-60-6 Isobutyric acid (1S,4S,6R)-2-bromo-4-(tert-butyl-dimethyl-silanyloxy)-6-methyl-cyclohex-2-enyl ester 
• 473536-51-5 (1S,4S,6R)-4-[(tert-butyldimethylsilyl)oxy]-6-methyl-2-vinyl-2-cyclohexen-1-yl-isobutyrate 

Relevant academic research and scientific papers

Enantioselective total synthesis of angucyclinone-type antibiotics rubiginones A2 and C2

The tetracyclic skeleton of C4-oxygenated angucyclinone-type antibiotics rubiginones A2 ((+)-3) and C2 ((-)-4) is constructed by Diels-Alder reaction of a racemic sulfinyl-substituted methyl juglone and the enantiopure vinyl cyclohex