473596-59-7Relevant academic research and scientific papers
Achieving vinylic selectivity in Mizoroki-heck reaction of cyclic olefins
Wu, Xiaojin,Lu, Yunpeng,Hirao, Hajime,Zhou, Jianrong
supporting information, p. 6014 - 6020 (2013/06/26)
In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium-hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions. Copyright
One-pot Negishi cross-coupling reactions of in situ generated zinc reagents with aryl chlorides, bromides, and triflates
Sase, Shohei,Jaric, Milica,Metzger, Albrecht,Malakhov, Vladimir,Knochel, Paul
supporting information; experimental part, p. 7380 - 7382 (2009/05/07)
(Chemical Equation Presented) In situ generated aryl, heteroaryl, alkyl, or benzylic poly-functional zinc reagents obtained by the addition of zinc and LiCl to the corresponding organic iodides undergo smooth Pd(0)-catalyzed cross-coupling reactions with
Novel cyclohexenyl phenyl diazepines vasopressin and oxytocin receptor modulators
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, (2008/06/13)
The present invention provides novel tricyclic diazepine compounds and methods and pharmaceutical compositions utilizing them for the treating or preventing disorders including diabetes insipidus, nocturnal enuresis, nocturia, urinary incontinence, bleedi
