473980-96-0

Basic information

• Product Name: (S)-2-[(E)-2-phenylvinyl]oxirane
• Synonyms: (S)-2-[(E)-2-phenylvinyl]oxirane
• CAS NO: 473980-96-0
• Molecular Weight: 146.189
• Mol File: 473980-96-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-2-[(E)-2-phenylvinyl]oxirane(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-[(E)-2-phenylvinyl]oxirane(473980-96-0)
• EPA Substance Registry System: (S)-2-[(E)-2-phenylvinyl]oxirane(473980-96-0)

Safety Data

• Hazardous Substances Data: 473980-96-0(Hazardous Substances Data)

Upstream product

• 229648-88-8 (2S,3E)-4-phenylbut-3-ene-1,2-diol 
• 111324-03-9 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-2Λ⁵,4Λ⁵-catenadi(phosphazene) 
• 104-55-2 3-phenyl-propenal 
• 1021153-94-5 (2S,3E)-1-chloro-4-phenylbut-3-en-2-yl acetate 

Downstream Products

• 13891-95-7 (1E,3R)-1-phenyl-1,5-hexadien-3-ol 
• 22639-28-7 (R)-goniothalamin 
• 473980-97-1 (E)-(R)-5-Hydroxy-7-phenyl-hept-6-en-2-ynoic acid 

Relevant articles and documents

Highly enantioselective ylide-mediated synthesis of terminal epoxides

The highly efficient asymmetric epoxidation of aldehydes by methylene transfer is now possible using new sulfonium salts. This journal is

A concise enantioselective strategy to (+)-(R)-goniothalamin and (+)-(R)-goniothalamin oxide by employing hydrolytic kinetic resolution and ring-closing metathesis as key steps

An efficient and general strategy to (R)-goniothalamin and (R)-goniothalamin oxide is described by using Jacobsen's hydrolytic kinetic resolution of racemic epoxide and ring-closing metathesis (RCM) as key steps, which provided a rapid access to these natural products that display a fascinating array of biological activity. (R)-Goniothalamin oxide was prepared in high yield and diastereomeric excess under various epoxidation conditions. Georg Thieme Verlag Stuttgart.