474-75-9Relevant articles and documents
Studies on organic fluorine compounds. XVI. Stereochemistry in fluorination of sterols with phenylfluorophosphoranes
Kobayashi,Kumadaki,Ohsawa,et al.
, p. 196 - 200 (1975)
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Coxon,J.M. et al.
, p. 51 - 58 (1969)
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A Series of Deoxyfluorination Reagents Featuring OCF2Functional Groups
Cao, Wei,Chen, Qing-Yun,Guo, Yong,Su, Zhaoben,Wu, Chengying,Zhao, Shiyu
supporting information, (2020/11/03)
Research on perfluoroalkyl ether carboxylic acids (PFECAs) as alternatives for perfluoroalkyl substances continues with the goal of protecting the environment. However, very little is known about the utilization of decomposition products of PFECAs. We report herein a new series of deoxyfluorination reagents featuring OCF2 functional groups derived from certain PFECAs. Alkyl fluorides were generated from various alcohols in ≤97% yield by these novel reagents. The mechanistic experiment verified in situ generation of carbonic difluoride (COF2).
Observations on the Reaction of Xanthate Esters with 4-Methyl(difluoroiodo)benzene: a New Method for the Conversion of Alcohols to Alkyl Fluorides
Koen, Mark J.,Guyader, Frederic Le,Motherwell, William B.
, p. 1241 - 1242 (2007/10/02)
Treatment of a range of S-methyldithiocarbonates (xanthates) with 4-methyl(difluoroiodo)benzene gives the corresponding alkyl fluorides.