474103-70-3

Upstream product

• 498555-13-8 (4R,5R)-4-[(4R,5R)-5-(1-Hydroxy-prop-2-ynyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,2-dimethyl-[1,3]dioxan-5-ol 
• 1005-56-7 phenylcarbonochloridothioate 
• 498555-14-9 Carbonic acid ethyl ester 1-[(4R,5S)-5-((4R,5R)-5-hydroxy-2,2-dimethyl-[1,3]dioxan-4-yl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-prop-2-ynyl ester 

Downstream Products

• 156619-09-9 (1S,2R,3S,4R,5S)-5-hydroxymethyl-cyclohexane-1,2,3,4-tetraol 
• 716320-21-7 (3aS,4R,5S,6S,7S,7aR)-6,7-Bis-benzyloxy-5-hydroxymethyl-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-ol 
• 474103-80-5 (3aR,4S,5S,5aR,9aR,9bS)-4,5-Bis-benzyloxy-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxine 
• 716320-19-3 (3aR,4S,5aR,9aR,9bS)-4-Benzyloxy-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-5-ol 
• 716320-18-2 (3aS,4R,5aS,9aR,9bS)-4-Benzyloxy-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-5-one 
• 716320-26-2 ((3aS,5S,7S,7aS)-7-Benzyloxy-2,2-dimethyl-6-methylene-hexahydro-benzo[1,3]dioxol-5-ylmethoxy)-tert-butyl-diphenyl-silane 
• 716320-27-3 (3aS,4S,5R,6R,7aS)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-ol 
• 716320-25-1 (3aS,4R,5S,7S,7aR)-7-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-6-methylene-hexahydro-benzo[1,3]dioxol-4-ol 
• 716320-23-9 ((3aS,5R,6S,7S,7aS)-6,7-Bis-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-ylmethoxy)-tert-butyl-diphenyl-silane 
• 716320-22-8 (3aS,4R,5S,6S,7S,7aR)-6,7-Bis-benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-ol 

Relevant academic research and scientific papers

A combined, 6-exo-dig radical cyclization-palladium catalyzed allylic amination, approach to aminocarbasugar analogs: Synthesis of novel N-substituted aminocyclitols from D-mannose

A novel approach, which features a stereoselective 6-exo-dig radical cyclization and a palladium-catalyzed allylic amination, permits a six steps synthesis of aminocyclitol analogs from D-mannose.

A stereodivergent approach to 5a-carba-α-D-gluco-, -α-D-galacto and -β-L-gulopyranose pentaacetates from D-mannose, based on 6-exo-dig radical cyclization and Barton-Mccombie radical deoxygenation

The three carbasugars, 5a-carba-α-D-gluco-, -α-D-galacto and -β-L-gulopyranose pentaacetates 42, 35 and 28 respectively, have been prepared in a stereodivergent manner from D-mannose. Alkynyl derivatives of 2,3:4,6-di-O-isopropylidene-D-mannopyranose, whi