716320-19-3

Upstream product

• 474103-70-3 Carbonic acid 1-[(4R,5R)-5-((4R,5R)-2,2-dimethyl-5-phenoxythiocarbonyloxy-[1,3]dioxan-4-yl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-prop-2-ynyl ester ethyl ester 
• 498555-14-9 Carbonic acid ethyl ester 1-[(4R,5S)-5-((4R,5R)-5-hydroxy-2,2-dimethyl-[1,3]dioxan-4-yl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-prop-2-ynyl ester 
• 474103-74-7 Carbonic acid ethyl ester (3aR,4S,5aS,9aR,9bS)-2,2,8,8-tetramethyl-5-methylene-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-yl ester 
• 474103-98-5 (3aR,4S,5aS,9aR,9bS)-4-Benzyloxy-2,2,8,8-tetramethyl-5-methylene-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxine 
• 498555-13-8 (4R,5R)-4-[(4R,5R)-5-(1-Hydroxy-prop-2-ynyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,2-dimethyl-[1,3]dioxan-5-ol 
• 474103-76-9 (3aR,4S,5aS,9aR,9bS)-2,2,8,8-Tetramethyl-5-methylene-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-ol 
• 716320-18-2 (3aS,4R,5aS,9aR,9bS)-4-Benzyloxy-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-5-one 

Downstream Products

• 474103-92-9 (3aR,4S,5aS,9aR,9bS)-4-Benzyloxy-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxine 
• 156619-09-9 (1S,2R,3S,4R,5S)-5-hydroxymethyl-cyclohexane-1,2,3,4-tetraol 

Relevant academic research and scientific papers

A stereodivergent approach to 5a-carba-α-D-gluco-, -α-D-galacto and -β-L-gulopyranose pentaacetates from D-mannose, based on 6-exo-dig radical cyclization and Barton-Mccombie radical deoxygenation

The three carbasugars, 5a-carba-α-D-gluco-, -α-D-galacto and -β-L-gulopyranose pentaacetates 42, 35 and 28 respectively, have been prepared in a stereodivergent manner from D-mannose. Alkynyl derivatives of 2,3:4,6-di-O-isopropylidene-D-mannopyranose, whi