474304-44-4Relevant academic research and scientific papers
A synthesis of diketones from carbonyl compounds and α,ω-dichloro-α,ω-disulfinylalkanes with two carbon-carbon bond-formation via bis-sulfinyloxiranes
Satoh, Tsuyoshi,Taguchi, Daisaku,Kurabayashi, Aki,Kanoto, Makiko
, p. 4217 - 4224 (2007/10/03)
Bis-sulfinyloxiranes were synthesized in two steps from carbonyl compounds and α,ω-dichloro-α,ω-disulfinylalkanes, which were synthesized from α,ω-dibromoalkanes in three steps, in good yields. Treatment of the bis-sulfinyloxiranes with sodium benzenethiolate and piperidine gave α,α′-di(phenylthio) diketones and α,α′-diamino diketones, respectively, in high yields. From these products, some kinds of diketones were synthesized in good to high yields.
