474459-57-9

Upstream product

• 474459-59-1 3-O-t-butyldimethylsilyl-4-O-mesyl-6-O-trityl-D-glucal 
• 474459-58-0 3-O-t-butyldimethylsilyl-6-O-trityl-D-glucal 
• 2873-29-2 D-glucal triacetate 
• 122350-80-5 1,5-anhydro-2-deoxy-6-O-trityl-D-arabino-hex-1-enitol 

Downstream Products

• 55735-66-5 ethyl 2,3-dideoxy-6-O-trityl-α-D-threo-hex-2-enopyranoside 
• 474459-61-5 ethyl-6-O-trityl-2,3-dideoxy-β-D-threo-hex-2-enopyranoside 
• 825638-51-5 6-O-trityl-3-deoxy-3-azido-D-galactal 
• 825638-48-0 6-O-trityl-3-deoxy-3-azido-D-gulal 
• 1057522-11-8 6-O-trityl-4-O-(trimethylsilyloxy)-2,3-dideoxy-β-D-threo-hex-2-enopyranosyl azide 
• 825638-33-3 (1R,2R,6R)-2-Trityloxymethyl-3,7-dioxa-bicyclo[4.1.0]hept-4-ene 
• 871590-07-7 (2R,3R)-6-(3,4-Dimethoxy-benzyloxy)-2-trityloxymethyl-3,6-dihydro-2H-pyran-3-ol 

Relevant academic research and scientific papers

Regio- and stereoselectivity of the addition of O-, S-, N-, and C-nucleophiles to the β vinyl oxirane derived from D-glucal

6-O-Trityl- (1a) and 6-(O-benzyl)-substituted epoxide (1b) derived from D-glucal were examined in their addition reactions with O-, C-, N-, and S-nucleophiles. A 1,4-regio- and β-stereoselective or an anti 1,2-addition pathway is commonly observed dependi

New stereoselective beta-glycosylation via a vinyl oxirane derived from D-glucal.

[reaction: see text] The reaction of the vinyl oxirane 1 derived from D-glucal with a series of O-nucleophiles (alcohols, phenol, and diacetone D-glucose) affords the corresponding 2-unsaturated beta-O-glycosides in a completely stereoselective way (syn 1