474687-12-2

Upstream product

• 412356-78-6 dibromo(2,6-diisopropylphenyl)(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)germane 
• 583-53-9 2,3-dibromobenzene 

Downstream Products

• 474687-16-6 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,6-diisopropylphenyl)Ge(phenyl)(OH) 
• 847335-81-3 2-(2,6-diisopropylphenyl)-2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2H-benzo[c][1,2]telluragermete 
• 847335-79-9 2-(2,6-diisopropylphenyl)-2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2H-benzo[c][1,2]thiagermete 
• 847335-80-2 2-(2,6-diisopropylphenyl)-2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2H-benzo[c][1,2]selenagermete 

Relevant academic research and scientific papers

Synthesis and isolation of the first germacyclopropabenzene: A study to elucidate the intrinsic factor for the ring deformation of cyclopropabenzene skeletons

A study was performed to elucidate the intrinsic factor for the ring deformation of cyclopropabenzene skeletons. The treatment of an overcrowded diaryldilithiogermane, Tbt(Dip)GeLi2 (Tbt = 2,4,6,-tris[bis(trim-ethylsilyl)methyl]phenyl; Dip = 2,6-diisopropylphenyl), generated by exhaustive reduction of the corresponding dibromogermane Tbt(Dip)GeBr2, with 1,2-dibromobenzene resulted in the isolation of the germacyclopropabenzene. The experimental results were in good agreement with those obtained by theoretical calculations.