474766-50-2Relevant academic research and scientific papers
Synthesis and properties of 2-Alkoxy- and 2-alkylthio- -3-aryl(hetaryl) propenals
Keiko, Natalia A.,Stepanova, Ludmila G.,Verochkina, Ekaterina A.,Larina, Ludmila I.
experimental part, p. 49 - 60 (2010/07/20)
2-Alkoxy- and 2-alkylthio-3-aryl(hetaryl)propenals have been synthesized in 57-84% yields by the reaction of aldol condensation of aryl(hetaryl) aldehydes with 2-alkoxy- and 2-butylthioacetaldehydes. In the presence of alkali catalysts the reaction proceeds stereoselectively in two-phase systems. The direction of the?=? bond hydration of the prepared enals in the course of hydrolysis in acidic medium has been investigated.
