474924-65-7

Upstream product

• 18437-68-8 tert-butyl N-(4-methoxyphenyl)carbamate 
• 106-95-6 allyl bromide 
• 104-94-9 4-methoxy-aniline 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 528869-41-2 (Z)-(4-hydroxy-6-phenyl-hex-1-enyl)-(4-methoxy-phenyl)-carbamic acid tert-butyl ester 
• 1380209-15-3 2-allyl-1-azido-4-methoxybenzene 
• 68267-68-5 2-allyl-4-methoxyaniline 
• 1374693-94-3 C₂₈H₃₁NO₇S 
• 1361121-57-4 C₂₀H₂₁NO₃S 
• 66236-30-4 C₁₇H₁₉NO₃S 
• 1361121-48-3 (E)-4-methoxy-2-(prop-1-en-1-yl)aniline 
• 71954-46-6 N-allyl-4-methoxyaniline 

Relevant academic research and scientific papers

Synthesis of indolines, indoles, and benzopyrrolizidinones from simple aryl azides

A simple approach to prepare indolines and benzopyrrolizidinones from ortho-azidoallylbenzenes via a tandem radical addition/cyclization is described. The use of triethylborane to initiate and sustain the process provides the best results. Indolines are easily converted into the corresponding indoles by oxidation with manganese dioxide.

A new entry to the phenanthridine ring system

A new synthesis of phenanthridine derivatives having three-point diversity has been developed based on the sequential application of three-atom economic processes viz. aza-Claisen rearrangement, ring-closing enyne metathesis and Diels-Alder reaction as key steps. An unexpected isomerisation was observed during aza-Claisen rearrangement of N-allylanilines which may open up new opportunities in heterocyclic synthesis.

Pd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formation

We have developed an efficient Pd(II)-catalyzed enantioselective oxidative tandem cyclization strategy using molecular oxygen as a green oxidant for the double 5-exo-trig cyclizations of N-(2-allylaryl) amides to afford a variety of indolines in good yiel

Asymmetric carbon-carbon bond formations in conjugate additions of lithiated N-Boc allylic and benzylic amines to nitroalkenes: Enantioselective synthesis of substituted piperidines, pyrrolidines, and pyrimidinones

(-)-Sparteine mediated lithiations of N-Boc-allylic and benzylic amines provide configurationally stable intermediates which on conjugate additions to nitroalkenes provide highly enantioenriched enecarbamate products in good yields, and with high diastere