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476015-01-7

Pd(C(Me)=NXy)(Cl)(1,2-bis(diphenylphosphino)ethane) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 476015-01-7 Structure

  • Basic information

    1. Product Name: Pd(C(Me)=NXy)(Cl)(1,2-bis(diphenylphosphino)ethane)
    2. Synonyms:
    3. CAS NO:476015-01-7
    4. Molecular Formula:
    5. Molecular Weight: 686.509
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 476015-01-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Pd(C(Me)=NXy)(Cl)(1,2-bis(diphenylphosphino)ethane)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Pd(C(Me)=NXy)(Cl)(1,2-bis(diphenylphosphino)ethane)(476015-01-7)
    11. EPA Substance Registry System: Pd(C(Me)=NXy)(Cl)(1,2-bis(diphenylphosphino)ethane)(476015-01-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 476015-01-7(Hazardous Substances Data)

476015-01-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 476015-01-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,7,6,0,1 and 5 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 476015-01:
(8*4)+(7*7)+(6*6)+(5*0)+(4*1)+(3*5)+(2*0)+(1*1)=137
137 % 10 = 7
So 476015-01-7 is a valid CAS Registry Number.

476015-01-7Relevant articles and documents

Influence of chelating phosphines on the insertion of isocyanides into palladium-methyl bonds in (P-P)Pd(Me)Cl complexes and their further reaction with olefins and isothiocyanates

Owen, Gareth R.,Vilar, Ra?on,White, Andrew J.P.,Williams, David J.

, p. 4799 - 4807 (2008/10/08)

A systematic study of the insertion reactions between (P-P)Pd(Me)Cl (where P-P = dppe, dppp, dppf) and CNR (where R = 2,6-dimethylphenyl, tert-butyl) is presented. The results have demonstrated that the insertion of CNR into the Pd-Me bond is highly dependent on the nature of the chelating phosphine. For the more strained complex formed with dppe, the insertion of isocyanides is slower and multiple insertion is not observed. This is in contrast to (dppp)Pd(Me)Cl, which reacts readily with isocyanides to produce single-, double-, and multiple-inserted products. Results analogous to those of dppp have been observed for the complexes with dppf, although the reactions are more controllable, indicating a less reactive complex. In an attempt to establish some structure-reactivity correlations, structural characterizations of (dppe)Pd{C(Me)=NXyl}Cl (1) and (dppp)Pd{(C=NXyl)(C(Me)=NXyl)}Cl (3) have been carried out. The structural parameters obtained are consistent with the observed reactivity. The reactions between (dppe)Pd{C(Me)=NXyl}Cl and unsaturated (olefins and isothiocyanates) species have also been studied. While norbornadiene (a strained diolefin) inserts into the palladium-iminoacyl bond, an addition is observed when reacting 1 with isothiocyanates.

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