47632-47-3Relevant academic research and scientific papers
2,2,5,5-TETRAMETHYL-2,5-DISILA-1-THIACYCLOPENTANE, AN EASILY PREPARED SULFUR TRANSFER REAGENT
Guggenheim, Thomas L.
, p. 6139 - 6140 (1987)
The title compound (3) has been prepared in good yield and is a useful sulfur transfer reagent.
Rhodium-catalyzed synthesis of diaryl sulfides using aryl fluorides and sulfur/organopolysulfides
Arisawa, Mieko,Ichikawa, Takuya,Yamaguchi, Masahiko
, p. 5318 - 5321 (2013/01/15)
Substituted pentafluorobenzenes react with sulfur to give bis(4-substituted 2,3,5,6-tetrafluorophenyl) sulfides in the presence of RhH(PPh 3)4, 1,2-bis(diphenylphosphino)benzene (dppBz), and tributylsilane. The reaction proceeds efficiently between room temperature and 80 °C. A comparative study of the reactivities of an organic trisulfide and a tetrasulfide showed notable substrate specificity. Di-tert-butyl tetrasulfide reacted with reactive aryl monofluorides and substituted pentafluorobenzenes. Di-tert-butyl trisulfide reacted with aryl monofluorides. The reactivity was explained on the basis of the difference in S-S bond energy.
Control of the "Superexchange" Interaction through Diphenyl Sulfide 4,4'-Diyl Magnetic Coupler by Changing the Oxidation State and Conformation of the Sulfur Atom
Matsuda, Kenji,Yamagata, Takehiro,Seta, Tomoo,Iwamura, Hiizu,Hori, Kenzi
, p. 8058 - 8064 (2007/10/03)
The exchange interaction between two triplet carbene centers through diphenyl sulfide 4,4'-diyl, its sulfoxide and sulfone analogs, and thiaxanthene 2,7-diyl coupling units was studied.Thse dicarbenes were generated by photolysis of the corresponding bisd
Effect of the Oxidation State of the Sulfur Atom on the Exchange Interaction between Two Triplet Carbene Units through Diphenyl Sulfide p,p'-Diyl Couplers
Matsuda, Kenji,Yamagata, Takehiro,Iwamura, Hiizu
, p. 1085 - 1086 (2007/10/03)
The exchange interaction between two triplet carbene centers through diphenyl sulfide p,p'-diyl and the corresponding sulfoxide coupling units was studied.While the former was found to by a ferromnagnetic coupler, the latter was found to by an antiferroma
Bis(diphenylaminomethane) antimicrobial agents
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, (2008/06/13)
New chemicals containing two diphenylaminomethane groups, linked together by a moiety other than oxygen, e.g., 1,2-bis[4-(3-methyl-alpha-aminobenzyl)phenoxy]ethane, are effective antimicrobial agents useful as agricultural or industrial fungicides and bactericides.
