47658-53-7Relevant academic research and scientific papers
Transition Metal Compound and Catalyst Composition Comprising Same
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, (2022/02/05)
A novel transition metal compound and a catalyst composition including same are disclosed herein. In some embodiments, the transition metal compound is represented by formula 1 disclosed herein. In some embodiments, the catalyst composition comprises the transition metal compound represented by formula 1. The catalyst composition may be useful for preparing an olefin-based polymer having a high molecular weight in a low density region, and may be useful for preparing an olefin-based polymer having a low melting index (MI) in high temperature conditions and a high molecular weight.
Tetraorganylborate salts as convenient precursors for photogeneration of tertiary amines
Sarker, Ananda M.,Lungu, Adrian,Mejiritski, Alexander,Kaneko, Yuji,Neckers, Douglas C.
, p. 2315 - 2331 (2007/10/03)
Photoreactions of p-(benzoyl)benzyl trisubstituted ammonium tetraorganylborate salts for the generation of tertiary amines in solution and rigid matrices are described. Structural modification of the complexes allows study of the influence of steric and electronic effects on the photogeneration of amines. Flash photolysis, cyclic voltammetry and product analysis indicate that single electron transfer from borate to excited benzophenone is followed by homolytic C-N bond cleavage. Photoliberation of the tertiary amine is controlled by the rate of the electron transfer reaction.
Photoinduced Inter- and Intra-Ion-Pair Electron Transfer Reactions in N-(p-Benzoylbenzyl)-N,N,N-tri-n-butylammonium Triphenyl-n-butylborate and -Gallate Salts
Hassoon, S.,Sarker, A.,Polykarpov, A. Y.,Rodgers, N. A. J.,Neckers, D. C.
, p. 12386 - 12393 (2007/10/03)
The protoreduction of N-(p-benzoylbenzyl)-N,N,N-tri-n-butylammonium triphenyl-n-butylborate (1) and gallate (2) was studied using nano- and picosecond laser flash photolysis.An electron transfer reaction from the borate or the galate counteranion to the excited triplet state of the benzophenone moiety (BP*3) was demonstrated.This reaction leads to the formation of benzophenone radical anion (6) and the boranyl radical, the latter of which dissociates rapidly to form butyl radical.The electron transfer rate was found to depend on the polarity of the solvent.In neat benzene, the short lifetime of the triplet obtained (300 +/- 150 ps) indicates an intramolecular process and that the compounds exist as tight ion pairs.The addition of 1percent MeCN increases the triplet lifetime up to 1.2 ns.The formation of a solvent-separated ion pair was suggested in this solvent mixture.However, in the polar solvent MaCN, 1 and 2 exist partially as free ions as determined by their dissociation constants.A diffusion-controlled intermolecular electron transfer process was shown in this solvent.The p-benzyloxybenzyl radical (BPCH2.), most likely formed by the C-N cleavage bond in the radical anion (6), was identified as an intermediate in the reaction pathway.After the initial electron transfer reaction, this produced tributylamine.The quantum yield obtained for the reaction of 1, 1E-2 M in MeCN, is 0.5 +/- 0.05.Triplet quenching as well as coupling of the radical anion (6) with the butyl radical deriving from decomposition of the borate was suggested to complete with the C-N cleavage reaction.
