476682-67-4Relevant academic research and scientific papers
Pinacol rearrangement for constructing asymmetric centers adjacent to heterocycles
Shinohara, Tomoichi,Suzuki, Keisuke
, p. 6937 - 6940 (2002)
Stereospecific pinacol-type 1,2-shift of electron-rich heterocycles was achieved under organoaluminum-promoted conditions to afford optically pure ketones or alcohols possessing these heterocycles. The method was applied to the asymmetric formal total synthesis of indolmycin.
