477332-49-3Relevant academic research and scientific papers
Cyclohexadienyl niobium complexes and arene hydrogenation catalysis
Fryzuk, Michael D.,Kozak, Christopher M.,Bowdridge, Michael R.,Patrick, Brian O.
, p. 5047 - 5054 (2002)
Hydrogenolysis of R[P2N2]NbCH2SiMe3 (where R[P2N2] = RP(CH2SiMe2NSiMe2CH2)2PR; R = cyclohexyl, Cy, or phenyl, Ph) in benzene or toluene causes hydride addition to the aromatic solvent resulting in the formation of the π-bonded complexes R[P2N2]Nb(η5-C6H 7) (R = Cy, 1; R = Ph, 2) and R[P2N2]Nb(η5-C7H 9) (R = Cy, 3; R = Ph, 4) in benzene and toluene, respectively. Performing the hydrogenation at a higher pressure of 29 atm at room temperature causes the catalytic hydrogenation of benzene to cyclohexane as determined by NMR spectroscopy and GC-MS analysis. The hydrogenation of toluene to methylcyclohexane can also be performed, but the turnover frequency is considerably lower. Examination of the solid residues from the high-pressure hydrogenations indicates the formation of the π-bonded complexes 1 and 2. The addition of 29 atm of H2 to these cyclohexadienyl derivatives in benzene or toluene, however, shows no hydrogenation products, indicating these species are not catalytically active.
