477559-18-5Relevant academic research and scientific papers
Enantioselective rhodium-catalyzed hydrogenation of enol carbamates in the presence of monodentate phosphines
Enthaler, Stephan,Erre, Giulia,Junge, Kathrin,Michalik, Dirk,Spannenberg, Anke,Marras, Fabrizio,Gladiali, Serafino,Beller, Matthias
, p. 1288 - 1298 (2007)
The rhodium-catalyzed asymmetric hydrogenation of different acyclic and cyclic enol carbamates to give optically active carbamates has been examined in the presence of chiral monodentate ligands based on a 4,5-dihydro-3H-dinaphthophosphepine motif 4. The
Synthesis of new chiral monodentate phosphines and their use in asymmetric hydrogenation
Junge, Kathrin,Oehme, Günther,Monsees, Axel,Riermeier, Thomas,Dingerdissen, Uwe,Beller, Matthias
, p. 4977 - 4980 (2007/10/03)
A general synthesis of chiral 4,5-dihydro-3H-dinaphthophosphepines 1a-g is described. The resulting ligands represent a new class of monodentate chiral phosphines. First applications of 1a-g in the rhodium-catalyzed asymmetric hydrogenation of unsaturated
