477781-62-7

Upstream product

• 238757-51-2 (1S,5R,6S,7S,8S)-7-Benzyloxy-6,8-dimethyl-2,9-dioxa-bicyclo[3.3.1]nonan-3-one 
• 760978-01-6 endo-3-benzyloxy-endo,endo-2,4-dimethyl-8-oxabicyclo-[3.2.1]-octan-6-one 
• 171231-72-4 endo-3-benzyloxy-endo,endo-2,4-dimethyl-exo-6-hydroxy-8-oxabicyclo[3.2.1]octane 
• 96691-92-8 (1R,2R,3r,4S,5S)-3-(benzyloxy)-2,4-dimethyl-8-oxa-bicyclo[3.2.1]oct-6-ene 

Downstream Products

• 1403660-66-1 (2R,3R,4S,5R)-3-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-5-hydroxy-2,4-dimethylheptyl pivalate 
• 1403660-75-2 (2R,3R,4S,5R)-3-(benzyloxy)-5,7-dihydroxy-2,4-dimethylheptyl pivalate 
• 1403660-65-0 (2R,3R,4S)-3-(benzyloxy)-4-((R)-2,2-dimethyl-1,3-dioxan-4-yl)-2-methylpentyl pivalate 
• 1403660-73-0 ethyl 2-((R,4E,6E)-N-(2,4-dimethoxybenzyl)-6-methyl-3-oxo-8-((1R,3R,4S,5R)-1,4,8-tri-methyl-2,9-dioxabicyclo[3.3.1]non-7-en-3-yl)nona-4,6-dienamido)acetate 
• 477781-57-0 (E)-(2R,3R,4R,8S,9S,10S)-1,3,9-Tris-benzyloxy-2,4,8-trimethyl-10-((4S,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-undec-6-en-5-one 
• 477781-59-2 ((3R,4R,5R)-4,6-Bis-benzyloxy-3,5-dimethyl-2-oxo-hexyl)-phosphonic acid dimethyl ester 
• 477781-64-9 (R)-4-((1S,2R,3R)-2,4-Bis-benzyloxy-1,3-dimethyl-butyl)-2,2-dimethyl-[1,3]dioxane 
• 477781-65-0 (3R,4S,5R,6R)-5,7-Bis-benzyloxy-4,6-dimethyl-heptane-1,3-diol 

Relevant academic research and scientific papers

Studies directed towards the total synthesis of polyether antibiotic ionomycin: Asymmetric synthesis of fragments C(24)-C(32) and C(1)-C(23)

A convergent and stereoselective approach for the synthesis of C1-C23 and C24-C32 segments of polyether antibiotic, ionomycin has been achieved. The key steps involved in this approach are the elaboration of two advanced fragments from a common precursor

Total synthesis of (?)-tirandamycin c utilizing a desymmetrization protocol

A highly stereoselective total synthesis of (?)-tirandamycin C has been achieved following a desymmetrization protocol developed in our group, Horner-Wadsworth-Emmons olefination, acid-catalyzed ketalization, Still-Gennari (Z)-selective olefination, and D

An efficient synthesis of (+)-prelactone B

An enantioselective synthesis of (+)-prelactone B 1 has been achieved on a multigram scale starting from a known bicyclic precursor 2. The key feature of the strategy is the generation of 3-stereogenic centres from a single bicyclic precursor, which has b

A stereoconvergent synthesis of the C(19)-C(31) fragment of scytophycin C

The C(19)-C(31) fragment of the anti-tumor macrolide, scytophycin C, was realized in a stereoconvergent manner utilizing a desymmetrization approach to create eight contiguous asymmetric centers from a common precursor.