477868-24-9Relevant academic research and scientific papers
The combination of organometallic {Mo(η3-allyl)(CO)2(phen)} fragments and hard aquo and hydroxo ligands: Controlled synthesis and structural characterization
Morales, Dolores,Elena Navarro Clemente,Pérez, Julio,Riera, Lucía,Riera, Víctor,Miguel, Daniel
, p. 4934 - 4938 (2002)
The reaction of [Mo(η3-C3H4-Me-2)Cl(CO)2(phen)] with NaBAr′4 (Ar′ = 3,5-bis(trifluoromethyl)phenyl) and H2O allowed the isolation of the aquo complex [Mo(η3-C3H4-Me-2)(OH2)(CO)2 (phen)]BAr′4·2Et2O (1). Deprotonation of 1 afforded a neutral monomeric hydroxo compound isolated as [{Mo(η3-C3H4-Me-2)(OH)(CO)2(phen )}2(μ-H2O)] (2), which could be also obtained by reaction of [Mo(η3-C3H4-Me-2)Cl(CO)2(phen)] with KOH in a biphasic CH2Cl2/ H2O medium. The reaction of 1 and 2 afforded the binuclear hydroxo-bridged compound [{Mo(η3-C3H4-Me-2)(CO)2(phen)} 2(μ-OH)]BAr′4 (3b) via nucleophilic substitution of water by the hydroxo ligand.
