477884-47-2Relevant academic research and scientific papers
Preparation of porphyrin-stoppered rotaxane aiming at immobilization on substrate
Asakawa, Masumi,Ikeda, Taichi,Yui, Nobuhiko,Shimizu, Toshimi
, p. 174 - 175 (2002)
The porphyrin-stoppered rotaxane was prepared from dibenzo-24-crown-8 (DB24C8) and the secondary ammonium ion derivative end-capped by the axial coordination of rhodium(III) tetra-(3,5-di-tert-butylphenyl) porphyrin [TBPP Rh(III) C1]. This rotaxane molecule was designed aiming at the immobilization on a substrate and the analysis of the physicochemical properties as a single molecule.
