478065-02-0Relevant articles and documents
Access to cyclic: Gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones
Adouama, Chérif,Keyrouz, Robert,Pilet, Guillaume,Monnereau, Cyrille,Gueyrard, David,No?l, Timothy,Médebielle, Maurice
supporting information, p. 5653 - 5656 (2017/07/07)
A variety of unprecedented scaffolds containing a difluoroacyl moiety were obtained in moderate to good yields, with excellent diastereoselectivity, via electrochemical or photochemical activation of difluoroacyl heteroaryles with a series of olefinic substrates.
Friedel-Crafts Fluoroacetylation of Indoles with Fluorinated Acetic Acids for the Synthesis of Fluoromethyl Indol-3-yl Ketones under Catalyst- and Additive-Free Conditions
Yao, Shun-Jiang,Ren, Zhi-Hui,Wang, Yao-Yu,Guan, Zheng-Hui
, p. 4226 - 4234 (2016/06/09)
A simple and efficient protocol for the fluoroacetylation of indoles is reported. The reaction uses fluorinated acetic acids as the fluoroacetylation reagents to synthesize diverse fluoromethyl indol-3-yl ketones in good yields under catalyst- and additive-free conditions. In addition, the only byproduct is water in this transformation. The synthetic utility of this reaction was also demonstrated by the concise synthesis of α-(trifluoromethyl)(indol-3-yl)methanol and indole-3-carboxylic acid.
N-(hetero)aryl indole derivatives as pesticides
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Page/Page column 24, (2008/06/13)
The invention relates to compounds of the general formula wherein R1, R2, R3, R4, R5, R6, A, X, m and n have the significances given in claim 1, and optionally the enantiomers thereof. The
