478184-27-9

Upstream product

• 478184-21-3 [5-triisopropylsilylethynyl-10,20-bis(2’,6’-bis(3,3-dimethylbutoxy)phenylporphinato)]zinc(II) 
• 478184-21-3 (5-(triisopropylethynyl)-10,20-bis(2,6-bis(3,3-dimethyl-1-butyloxy)phenyl)porphinato)zinc(II) 

Downstream Products

• 478184-19-9 [5-(4'-ethynyl-2,2';6',2''-terpyridyl)-10,20-bis(2',6'-bis(3,3-dimethyl-1-butyloxy)phenyl)porphinato]zinc(II) 
• 333363-20-5 bis[(5,5'-10,20-bis[2,6-bis(3,3-dimethyl-1-butyloxy)phenyl]porphyrinato)zinc(II)]ethyne 

Relevant academic research and scientific papers

The roles of molecular structure and effective optical symmetry in evolving dipolar chromophoric building blocks to potent octopolar nonlinear optical chromophores

A series of mono-, bis-, tris-, and tetrakis(porphinato)zinc(II) (PZn)-elaborated ruthenium(II) bis(terpyridine) (Ru) complexes have been synthesized in which an ethyne unit connects the macrocycle meso carbon atom to terpyridyl (tpy) 4-, 4′-, and 4′′-pos

Synthesis, spectroscopy, photophysics of multi-chromophoric ZN(II) group 8 metal complexes

Novel multichromophoric complexes comprising the formula[in-line-formulae]R1—RA-[MC]-([RM]z-[MC])m-RA—R2[/in-line-formulae]are provided. Polymeric compositions and devices comprising the same are also discussed. The complexes are characterized by a central bridging moiety comprising one or a plurality of linked conjugated macrocyclic molecules [MC] coupled to at least one inorganic moiety (R1 and/or R2) through organic linker RA. Preparation methods include metal-mediated cross-coupling techniques. The complexes can be useful in nonlinear optical devices and other optoelectronic applications.